JEE Main Practical Organic Chemistry Practice Questions With Solutions

Updated By Lam Vijaykanth on 21 Nov, 2025 17:35

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JEE Main Practical Organic Chemistry Practice Questions with Solutions

Practical Organic Chemistry deals with experimental and applied aspects of organic chemistry. The JEE Main Practical Organic Chemistry Practice Test is a valuable resource for students to practise and strengthen the practical organic chemistry area for success in the JEE Main exam. The JEE Main Practical Organic Chemistry Practice Questions with Solutions contain a variety of questions and their solutions from this topic. Practical Organic Chemistry is an important topic from the Chemistry section of the JEE Main entrance exam. You may expect 5 to 8 questions appearing from this part in the Chemistry section of the JEE Main exam. So, it is advised for students to make a well-defined preparation strategy and practice as many questions as possible to obtain maximum scores from this part.. Students can take the JEE Main Practical Organic Chemistry practice test at their preferred time, after which they can examine their performance and focus on the areas that need improvement.

The types of questions asked in the exam from the practical organic chemistry chapter are usually multiple-choice types, assertion-reason types, and match-type questions. The important topics from this chapter include Functional Group Analysis, Element Detection, Preparation of Organic Compounds, Purification Techniques, Quantitative & Qualitative Analysis, Chromatography, and Titrimetric Exercises. The JEE Main Practical Organic Chemistry Practice Test usually contains 15 to 20 questions from all these topics. Practising the JEE Main Practical Organic Chemistry Practice Questions with Solutions on a regular basis will help students to recall important formulas and answer questions from organic chemistry easily. It will also improve the speed at which the candidates solve questions during the real examination. JEE Main aspirants must solve at least one practice test on practical organic chemistry every week. This allows students to develop their accuracy and time management skills over time and have an effective JEE Main exam preparation. 

JEE Main Chemistry Practical Organic Chemistry Practice Questions

Question 1.

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Which of the following compound can give positive iodoform test when treated with aqueous KOH solution followed by potassium hypoiodite.

Question 2.

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Match List I with List II

LIST I
(Test)
LIST II
(Observation)
A.Br2 water testI.Yellow orange or orange red precipitate formed
B. Ceric ammonium nitrate testII.Reddish orange colour disappears
C.Ferric chloride testIII.Red colour appears
D.2, 4 - DNP testIV.Blue, Green, Violet or Red colour appear

Choose the correct answer from the options given below:

Question 3.

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Identify the incorrect statements regarding primary standard of titrimetric analysis.

(A) It should be purely available in dry form.

(B) It should not undergo chemical change in air.

(C) It should be hygroscopic and should react with another chemical instantaneously and stoichiometrically.

(D) It should be readily soluble in water.

(E) KMnO4 & NaOH can be used as primary standard.

Choose the correct answer from the options given below :

Question 4.

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Match List I with List II

LIST I
(Test)
LIST II
(Identification)
A.Bayer's testI.Phenol
B. Ceric ammonium nitrate testII.Aldehyde
C.Phthalein dye testIII.Alcoholic-OH group
D.Schiff's testIV.Unsaturation

Choose the correct answer from the options given below :

Question 5.

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Match List I with List II

LIST I
(Name of the test)
LIST II
(Reaction sequence involved) [M is metal]
A.Borax bead testI.MCO3MO+ΔCo(NO3)2CoOMO
B. Charcoal cavity testII.MCO3MCl2M2+
C.Cobalt nitrate testIII.MSO4ΔNa2B4O7M(BO2)2MBO2M
D.Flame testIV.MSO4ΔNa2CO3MCO3MOM

Choose the correct answer from the options given below:

Question 6.

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During the detection of acidic radical present in a salt, a student gets a pale yellow precipitate soluble with difficulty in NH4OH solution when sodium carbonate extract was first acidified with dil. HNO3 and then AgNO3 solution was added. This indicates presence of :

Question 7.

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The correct statement among the following, for a "chromatography" purification method is :

Question 8.

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Match List I with List II

LIST I
(Precipitating reagent and conditions)
LIST II
(Cation)
A.NH4Cl+NH4OHI.Mn2+
B. NH4OH+Na2CO3II.Pb2+
C.NH4OH+NH4Cl+H2S gas III.Al3+
D.dilute HClIV.Sr2+

Choose the correct answer from the options given below:

Question 9.

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Which of the following statements are correct?

A. Glycerol is purified by vacuum distillation because it decomposes at its normal boiling point.

B. Aniline can be purified by steam distillation as aniline is miscible in water.

C. Ethanol can be separated from ethanol water mixture by azeotropic distillation because it forms azeotrope.

D. An organic compound is pure, if mixed M.P. is remained same.

Choose the most appropriate answer from the options given below :

Question 10.

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In the precipitation of the iron group (III) in qualitative analysis, ammonium chloride is added before adding ammonium hydroxide to :

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Question 1.

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In Kjeldahl's method for estimation of nitrogen, CuSO4 acts as :

Question 2.

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Given below are two statements :

Statement (I) : Potassium hydrogen phthalate is a primary standard for standardisation of sodium hydroxide solution.

Statement (II) : In this titration phenolphthalein can be used as indicator.

In the light of the above statements, choose the most appropriate answer from the options given below :

Question 3.

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The fragrance of flowers is due to the presence of some steam volatile organic compounds called essential oils. These are generally insoluble in water at room temperature but are miscible with water vapour in vapour phase. A suitable method for the extraction of these oils from the flowers is -

Question 4.

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Match List I with List II

List - I (Technique)List - II (Application
(A)Distillation(I)Separation of glycerol from spent-lye
(B)Fractional distillation(II)Aniline - Water mixture
(C)Steam distillation(III)Separation of crude oil fractions
(D)Distillation under reduced pressure(IV)Chloroform - Aniline

Choose the correct answer from the options given below:

Question 5.

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Chromatographic technique/s based on the principle of differential adsorption is / are

A. Column chromatography

B. Thin layer chromatography

C. Paper chromatography

Choose the most appropriate answer from the options given below:

Question 6.

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In chromyl chloride test for confirmation of Cl ion, a yellow solution is obtained. Acidification of the solution and addition of amyl alcohol and 10%H2O2 turns organic layer blue indicating formation of chromium pentoxide. The oxidation state of chromium in that is

Question 7.

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Appearance of blood red colour, on treatment of the sodium fusion extract of an organic compound with FeSO4 in presence of concentrated H2SO4 indicates the presence of element/s

Question 8.

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The technique used for purification of steam volatile water immiscible substances is :

Question 9.

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In the wet tests for detection of various cations by precipitation, Ba2+ cations are detected by obtaining precipitate of

Question 10.

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When a solution of mixture having two inorganic salts was treated with freshly prepared ferrous sulphate in acidic medium, a dark brown ring was formed whereas on treatment with neutral FeCl3, it gave deep red colour which disppeared on boiling and a brown red ppt was formed. The mixture contains :

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