Updated By Lam Vijaykanth on 29 Sep, 2025 12:34
The JEE Main Haloalkanes and Haloarenes Practice Test is an essential resource for all JEE Main aspirants to learn about the main concepts of Haloalkanes and Haloarenes and improve their knowledge of this chapter. The JEE Main Haloalkanes and Haloarenes Practice Questions with Solutions have a variety of questions from Haloalkanes and Haloarenes for students to practice and strengthen their chemistry section for the JEE Main entrance test.
About 2 to 3 questions may appear from Haloalkanes and Haloarenes on the JEE Main question paper. Usually, the question will be in the form of multiple choice questions as well as integer type questions, testing your conceptual knowledge of organic chemistry. JEE Main is a highly competitive entrance exam for all engineering aspirants. Therefore, it is essential for candidates to attempt these practice tests at least once a week to develop knowledge and precision of the topic.
Around 15 to 20 questions are available from this chapter in the JEE Main Haloalkanes and Haloarenes Practice Questions with Solutions, covering all the essential topics. The important topics of the Haloalkanes and Haloarenes chapter, from which questions may appear, are Nomenclature & Structure of Haloalkanes & Haloarenes, Physical Properties of Haloalkanes & Haloarenes, Chemical Properties of Haloalkanes & Haloarenes, Preparation Methods, Conversions & Multi-step Reactions, and Reactivity & Comparisons. The practice tests, containing questions on all these topics along with their detailed solutions, will allow aspirants to understand the basic concepts well by going through the detailed explanations provided.
Thoroughly practising the JEE Main Haloalkanes and Haloarenes Practice Questions with Solutions on a regular basis will help students to improve their accuracy and manage their time better during the examination. It will also allow them to understand their weak areas, work on them, and gain confidence in solving questions from this topic with ease in the JEE Main exam.
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) :
Reason (R) : The partially bonded unhybridized p-orbital that develops in the trigonal bipyramidal transition state is stabilized by conjugation with the phenyl ring.
In the light of the above statements, choose the most appropriate answer from the options given below :
In the following sequence of reaction, the major products B and C respectively are :

Which among the following compounds will undergo fastest SN2 reaction.
Identify the major product in the following reaction.


Product P is

Consider the above reactions, identify product B and product C.
Find out the major product formed from the following reaction.


Identify B and C and how are A and C related?
Identify the correct set of reagents or reaction conditions '

Identify A and B in the following reaction sequence.

The product (C) in the below mentioned reaction is :
Given below are two statements:
Statement - I: High concentration of strong nucleophilic reagent with secondary alkyl halides which do not have bulky substituents will follow
Statement - II: A secondary alkyl halide when treated with a large excess of ethanol follows
In the light of the above statements, choose the most appropriate from the options given below:
Example of vinylic halide is :
The final product A, formed in the following multistep reaction sequence is :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) :
Reason (R) : Allyl halides are the compounds in which the halogen atom is attached to
In the light of the above statements, choose the most appropriate answer from the options given below :
Alkyl halide is converted into alkyl isocyanide by reaction with
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R :
Assertion A : Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom.
Reason R : Phenols react with halogen acids violently.
In the light of the above statements, choose the most appropriate from the options given below :
Identify B formed in the reaction.
Which among the following halide/s will not show
(A)
(B)
(C) 
(D) 
Choose the most appropriate answer from the options given below :
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