If the rate constant of a reaction is \(0.03 s^{-1}\) , how much time does it take for \(7.2\text { mol L}^{-1}\) concentration of the reactant to get reduced to \(0.9~\text {mol L} ^{-1}?\) (Given: log 2=0.301)
Question 2.
If the half-life \((t_{1/2})\) for a first order reaction is \(1~\text{minute}\), then the time required for \(99.9 \%\) completion of the reaction is closest to :
Question 3.
What is the rate constant for a reaction if the time taken by the first-order decomposition of \(\text{SO}_2\text{Cl}_2\) to decompose to 40% is 560 seconds? [Given: log 2.5 = 0.3979]
Question 4.
For a first-order reaction A \(\rightarrow\) Products, initial concentration of A is 0.1 M, which becomes 0.001 M after 5 minutes. Rate constant for the reaction in min-1 is
Question 5.
The half-life of a first-order reaction is 2000 years. If the concentration after 8000 years is 0.02 M, then the initial concentration was:
Question 6.
The rate constant for a first order reaction is . The time required to reduce 2.0 g of the reactant to 0.2 g is:
Question 7.
A first-order reaction has a rate constant of 2.303. The time required for 40 g of this reactant to reduce to 10 g will be
[Given that ]
Question 8.
If the rate constant for a first order reaction is k, the time (t) required for the completion of 99% of the reaction is given by:
Question 9.
A first-order reaction has a specific reaction rate of
10–2 sec–1. How much time will it take for 20 g of the reactant to reduce to 5 g?
Question 10.
The rate of a first-order reaction is 0.04 mol l–1 s–1 at 10 seconds and 0.03 mol l–1s–1 at 20 seconds after initiation of the reaction. The half-life period of the reaction is:
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Question 1.
In a zero-order reaction for every 10 °C rise of temperature, the rate is doubled.
If the temperature is increased from 10 °C to 100 °C, the rate of the reaction will become:
Question 2.
The half-life of a certain enzyme catalysed reaction is 138 s, that follow the 1st order kinetics. The time required for the concentration of the substance to fall from 1.28 mg L–1 to 0.04 mg L–1, is:
Question 3.
If 60% of a first-order reaction was completed in 60 min, 50% of the same reaction would be completed in approximately:
(log 4 = 0.60, log 5 = 0.69)
Question 4.
The reaction of hydrogen and iodine monochloride is given as:
H2(g) + 2ICl(g) → 2HCl(g) + I2(g)
This reaction is of first order with respect to H2(g) and ICl(g), for which of the following proposed mechanisms:
Mechanism A:
H2(g) + 2ICl(g) → 2HCl(g) + I2(g)
Mechanism B:
H2(g) + ICl(g) →HCl(g) + HI(g); slow
HI(g) + ICl(g) →HCl(g) + I2(g); fast
Question 5.
For a first-order reaction A → B the reaction rate at a reactant concentration of 0.01M is found to be . The half-life period of the reaction is:
Question 6.
The rate of a first-order reaction is 1.5 ×10–2 mol L–1 min–1at 0.5 M concentration of the reactant. The half-life of the reaction is:
Question 7.
The radioisotope, tritium has a half-life of 12.3 years. If the initial amount of tritium is 32 mg, how many milligrams of it would remain after 49.2 years:
Question 8.
The reaction A → B follows first-order kinetics. The time taken for 0.8 mol of A to produce 0.6 mol of B is 1 hour. The time taken for the conversion of 0.9 mol of A to produce 0.675 mol of B will be:
Question 9.
92U235, nucleus absorb a neutron and disintegrate in 54Xe139, 38Sr94 and x . The product x is:
Question 10.
A 300-gram radioactive sample has a half-life of 3 hours. After 18 hours the remaining quantity will be:
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