The standard heat of formation, in kcal/mol of \(Ba^{2+}\) is :
[Given : standard heat of formation of \(SO^{2-}_4\) ion (aq) \(= -216~ \text{kcal/mol}\), standard heat of crystallisation of \(BaSO_4 (s)= -4.5~\text{ kcal/mol,}\) standard heat of formation of \(BaSO_4 (s)= -349 ~\text{kcal/mol]}\)
Question 2.
Consider the following reaction: \(\mathrm{2H_2(g) + O_2(g) \rightarrow 2H_2O(g); ~\Delta_rH^\circ = -483.64~ kJ }\)
What is the enthalpy change (in KJ) for the decomposition of one mole of water?
Question 3.
At standard conditions, if the change in the enthalpy for the following reaction is –109 kJ mol–1
H2(g)+Br2(g)2HBr(g) and the bond energy of H2 and Br2 is 435 kJ mol–1 and 192 kJ mol–1 respectively, what is the bond energy (in kJ mol–1) of HBr?
Question 4.
The heat of combustion of carbon to CO2 is –393.5 KJ/mol. The heat released upon the formation of 35.2 g of CO2 from carbon and oxygen gas is:
Question 5.
The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 oC is:
Question 6.
Consider the following reactions:
Question 7.
The bond energy of H—H and Cl-Cl is 430 kJ
mol-1 and 240 kJ mol-1 respectively and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:
Question 8.
The enthalpy of combustion of H2, cyclohexene (C6H10) and cyclohexane (C6H12) are -241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is:
Question 9.
If the bond energies of H–H, Br – Br, and H –Br are 433, 192, and 364 kJ mol–1 respectively, the ∆Hº for the reaction H2(g) + Br2(g) → 2HBr(g) will be:
Question 10.
For which one of the following equations is equal to for the product:
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Question 1.
Heat of combustion ∆Hº for C(s), H2(g) and CH4(g) are – 94, – 68 and – 213 Kcal/mol. ∆Hº for C(s) + 2H2(g) → CH4 (g) is:
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